天然气水合物储层泥质细粉砂挡砂介质堵塞规律与微观挡砂机制

中国南海海域部分天然气水合物储层中地层砂为高泥质含量细粉砂，开采防控砂难度较大。针对高泥质细粉砂挡砂机制问题，使用粒度中值为10.13 μm的泥质细粉砂样品，模拟单向气液携砂流动条件，使用绕丝筛板、金属烧结网、金属纤维、预充填陶粒4类挡砂介质在20~80 μm挡砂精度下进行挡砂模拟实验，采用显微成像系统观察挡砂介质内部及表面砂粒沉积与堵塞动态，分析介质流通性能和挡砂性能变化，总结堵塞规律、微观挡砂机制与形态及其控制因素。研究结果表明，不同类型和精度的挡砂介质对泥质细粉砂的堵塞总体呈现堵塞开始、堵塞加剧和堵塞平衡3个阶段。随着驱替进行，挡砂介质渗透率逐渐降低，幅度会高达90%以上；同时过砂速度减缓，最终过砂率为5%~10%。根据堵塞规律和微观图像分析，提出了粗组分分选桥架、局部砂团适度挡砂、整体砂桥阻挡等挡砂介质对泥质细粉砂的3种微观挡砂机制。以粗组分分选桥架挡砂机制为主的挡砂工况下，挡砂介质堵塞渗透率较高，但过砂率超过15%，挡砂效果较差；以整体砂桥挡砂机制为主时，过砂率在10%以下，挡砂性能较好，但各类挡砂介质的堵塞渗透率不足1 D，流通性能较差。局部砂团适度挡砂机制为主时介质挡砂性能及流通性能介于两者之间。挡砂介质对天然气水合物储层泥质细粉砂的微观挡砂机制和形态受挡砂介质类型、精度、地层砂特征以及流动条件等因素控制，其规律对于水合物泥质细粉砂防控砂优化有指导意义。     

Improving water retention of chicken breast meats by CaCl2 combined with pulsed electric fields

Frozen poultry meat is the most widely consumed animal-based food. However, water loss often leads to quality loss of poultry meat. Therefore, the present study sought to investigate the combined effect of calcium chloride (CaCl₂) and pulsed electric fields (PEF) treatment on chicken breast meats and the mechanisms underlying protein degradation. The results showed that the synergistic effect was superior to the single treatment. Compared with the untreated group, the combination of CaCl₂ and PEF increased water holding capacity of chicken breast meats by 16.61% and decreased cooking loss by 28.93%. Low-field nuclear magnetic resonance (LF-NMR) results indicated that the synergistic treatment promoted water molecules' binding capacity in myofibrils of poultry meat, which exhibited higher immobilised water. Additionally, the combination of CaCl₂ and PEF led to increased degradation of proteins of high-molecular weight and surface hydrophobicity of myofibrillar protein. Furthermore, the extension of the protein molecule and microenvironmental changes promoted interaction between protein and water. In conclusion, the synergistic treatment of CaCl₂ and PEF enhanced water retention and improved physicochemical properties of the myofibrillar protein in chicken breast meats.     

Influence of soil density on gas permeability and water retention in soils amended with in-house produced biochar

Biochar has been used as an environment-friendly enhancer to improve the hydraulic properties(e.g.suction and water retention) of soil.However,variations in densities alter the properties of the soil-biochar mix.Such density variations are observed in agriculture(loosely compacted) and engineering(densely compacted) applications.The influence of biochar amendment on gas permeability of soil has been barely investigated,especially for soil with diffe rent densities.The maj or obj ective of this study is to investigate the water retention capacity,and gas permeability of biochar-amended soil(BAS) with different biochar contents under varying degree of compaction(DOC) conditions.In-house produced novel biochar was mixed with the soil at different amendment rates(i.e.biochar contents of 0%,5% and 10%).All BAS samples were compacted at three DOCs(65%,80% and 95%) in polyvinyl chloride(PVC)tubes.Each soil column was subjected to drying-wetting cycles,during which soil suction,water content,and gas permeability were measured.A simplified theoretical framework for estimating the void ratio of BAS was proposed.The experimental results reveal that the addition of biochar significantly decreased gas permeability k_g as compared with that of bare soil(BS).However,the addition of 5%biochar is found to be optimum in decreasing kg with an increase of DOC(i.e.k_(g,65%) k_(g,80%) k_(g,95%)) at a relatively low suction range(200 kPa) because both biochar and compaction treatment reduce the connected pores.     

平原地区城市湖泊防洪与景观功能协调研究——以枝江市金湖为例

为了使城市湖泊尽可能滞蓄雨洪、发挥景观功能、打造良好的居民"亲水空间",以枝江市金湖为例,根据金湖主要泄洪渠道的实际情况,利用Mike 21模型模拟计算汛限水位值,按照景观水位确定大、小洪水工况下合理的水位。在此基础上,提出传统的静态景观水位与改进的动态景观水位两种方案。结果表明:以50年一遇、30年一遇为代表的大洪水工况下合理景观水位为40.7 m,以20年一遇、10年一遇为代表的小洪水工况合理景观水位为41.3 m;静态方案采用50年一遇洪水计算结果为标准执行,将40.7 m作为金湖固定的景观水位;动态方案水位可在41.3~40.7 m之间波动;金湖适宜采用动态景观水位运行方案,水位可在40.7~41.3 m之间波动;根据短期预报及历史监测资料分析后合理调度,将41.3 m作为金湖常水位,确定预测洪水大小后调整水位迎战洪水。据此,可在充分利用水资源的同时有效协调景观高水位需求与防洪之间的矛盾。     

基于低影响开发理念的雨水控制设计计算

文中介绍了某电影文化综合体项目采用的集中雨水控制利用技术:透水性地面铺装、屋顶绿化、下凹式绿地、微生态雨水处理回用一体机。通过合理划分汇水面积,结合项目实际情况,计算给出了在限定年径流总量控制率的条件下,合理采用多种手段联合,使项目符合《绿色建筑评价标准》(GB/T 50378—2014)中的场地生态设计要求,实现了海绵城市的控制目标,也为类似工程提供了参考思路。     

Temporal and spatial evolution measurement of laser-induced breakdown spectroscopy on hydrogen retention in tantalum

Fuel retention measurement on plasma-facing components is an active field of study in magnetic confinement nuclear fusion devices.The laser-induced breakdown spectroscopy(LIBS)diagnostic method has been well demonstrated to detect the elemental distribution in PFCs.In this work,an upgraded co-axis LIBS system based on a linear fiber bundle collection system has been developed to measure the hydrogen(H) retention on a tantalum(Ta) sample under a vacuum condition.The spatial resolution measurement of the different positions of the LIBS plasma can be achieved simultaneously with varying delay times.The temporal and spatial evolution results of LIBS plasma emission show that the H plasma observably expands from the delay times of 0-200 ns.The diameter of Ta plasma is about 6 mm which is much less than the size of H plasma after 200 ns.The difference in the temporal and spatial evolution behaviors between H plasma and Ta plasma is due to the great difference in the atomic mass of H and Ta.The depth profile result shows that H retention mainly exists on the surface of the sample.The temporal and spatial evolution behaviors of the electron excited temperature are consistent with that of the Ta emission.The result will further improve the understanding of the evolution of the dynamics of LIBS plasma and optimize the current collection system of in situ LIBS in fusion devices.     

Novel superabsorbent materials from bacterial cellulose

A novel process for the production of superabsorbent materials (hydrogels) from bacterial cellulose (BC) was developed. Prior to crosslinking with a water‐soluble polyethylene glycol diacrylate (PEGDA), BC was first carboxymethylated and functionalized with glycidyl methacrylate. The degree of crosslinking influenced the swelling properties of the hydrogels. The use of greater amounts of PEGDA enhanced the formation of a thicker macromolecular network containing fewer capillary spaces in the crosslinked gel. The maximum water retention value of the hydrogels containing 2.5–3.5 mmol of carboxyl groups per gram of gel reached 125 g g^?1 in distilled water, and 29 g g^?1 in saline (0.9% NaCl solution). The highly porous hydrogel architecture with a pore size of 350–600 µm created a high specific surface area. This enables rapid mass penetration in superabsorbent applications. The superabsorbent hydrogels reached 80% of their maximum water absorption capacity in 30 min. © 2018 Society of Chemical Industry     

人工湿地-微生物电解池耦合系统的脱氮特性

实验构建了人工湿地-微生物电解池耦合系统（CW-MEC），并考察了CW-MEC在阴极有无曝气及不同水力停留时间（HRT）的条件下对生活污水的处理效果。实验结果显示，降低HRT会让CW-MEC阴极、阳极的COD去除率由91.11%±7.76%、86.58%±9.54%降低为77.81%±14.84%、81.44%±11.11%，氨氮去除率由58.54%±5.80%、58.22%±5.03%降低为48.04%±12.94%、48.27%±13.40%；阴极增加曝气会让CW-MEC阴极、阳极的COD去除率分别提高到89.51%±3.92%、82.40%±1.63%，阴极氨氮去除率提高到71.51%±16.44%，而阳极氨氮去除率不受影响；增加阴极曝气条件后，系统阴、阳极开始有硝酸盐氮积累，而CW-MEC阴极的硝酸盐氮含量明显低于对照组（CW-MFC）；通过电化学性能分析，相对于CW-MFC系统，CW-MEC具有更低的内阻；通过微生物多样性分析，CW-MEC系统具有更丰富的微生物多样性。     

Influence of polymer enhancement on water uptake,retention and barrier performance of geosynthetic clay liners

This paper explores the influence of polymer enhancement on water uptake and retention by geosynthetic clay liners (GCLs) across a wide suction range (up to 10⁶ kPa), including the low suction regime (0.1–10 kPa) typically omitted in past studies. The suction measurement methods used enabled elucidation of water uptake and retention behaviour through the framework of GCL pore structures and their corresponding suction regimes. Polymer enhanced GCLs (PE-GCLs) have high maximum water uptake, and both the water entry and air expulsion values tend to be high. Due to high swelling, the onset of geotextile confinement for PE-GCLs was observed at high suctions. The impact of polymer becomes more apparent when the bentonite achieves a pseudo-two-layer interlayer hydration state at a suction of about 40 MPa (RH = 75%). The hydration mechanism for the polymer fraction in bentonite is unique to the specific polymer type, polymer dosage, and manufacturing process. The water retention behaviour at the low suction range is caused by the in-filling of geotextile pores, bentonite swelling and extrusion, and polymer water adsorption. Insights from this study can form the basis for developing a more suitable bimodal generalised model for fitting the water retention curves of GCLs.